With the new feature on Skype for Android, users can now make and receive free Skype one-to-one video calls to other Skype users on the iPhone, Mac, Windows PCs and other Android phones.
To enjoy 2-way video calling on your Android device, it must be running Android version 2.3 and above with a front-facing camera. Supported handsets right now that allow video calling include the HTC Desire S, Sony Ericsson Xperia neo, Sony Ericsson Xperia pro and the Google Nexus S.
Check out the video below.
Download– Skype for Android[Source]- Skype